Quantum dot light-emitting diodes (QLEDs) have emerged as a cornerstone of next-generation display technology, renowned for their unmatched color purity and stability. Despite this promise, the traditional spin-coating methods commonly employed in QLED fabrication restrict scalability and drive-up costs, impeding their widespread adoption. While inkjet printing offers a scalable and cost-effective alternative, it faces obstacles such as suboptimal film uniformity and reduced device performance. To overcome these challenges and unleash the full potential of inkjet-printed QLEDs, a more profound investigation into post-processing techniques was imperative.
A collaborative research team from Nanjing University of Science and Technology, in along with international partners, has pioneered a novel pressure-assisted thermal annealing (PTA) strategy to transform inkjet-printed QLEDs. Published (DOI: 10.1016/j.esci.2023.100227) in eScience on December 29, 2023, the study highlights how PTA enables the creation of highly ordered quantum dot films, establishing new performance benchmarks. Remarkably, red QLEDs achieved a record-breaking EQE of 23.08%, marking a significant milestone in QLED innovation.
The researchers unveiled a transformative PTA process that redefines the quality of inkjet-printed QD films. Through meticulous control of solvent evaporation within a vacuum-assisted environment, the PTA technique produced films characterized by smoother surfaces and enhanced QD alignment. This innovative process yielded unparalleled film uniformity, with a root-mean-square roughness of a mere 0.54 nm, far surpassing conventional annealing methods.
The refined morphology of PTA-treated films dramatically bolstered charge transport and minimized defects, leading to extraordinary device performance. The red QLEDs realized a remarkable EQE of 23.08%, along with an operational lifetime that exceeded 343,342 hours at a brightness of 100 cd/m². Green QLEDs similarly showcased an impressive EQE of 22.43% and an operational lifetime that surpassed 1,500,463 hours. Additionally, the PTA approach has proven its scalability, maintaining uniformity across large-scale films. This breakthrough sets the stage for high-performance, cost-effective manufacturing of next-generation QLEDs.
“This breakthrough demonstrates the transformative potential of the PTA strategy in surmounting the challenges associated with inkjet-printed QLEDs,” stated Prof. Dr. Haibo Zeng, the study’s lead researcher. ” Attaining such remarkable efficiency and stability underscores the precision and scalability inherent in our approach, heralding a new era for display technology.”
The PTA process presents a scalable and cost-effective manufacturing solution for high-performance QLEDs, with applications that reach beyond the realm of displays to encompass lighting and optoelectronics. By lowering production costs and significantly enhancing device longevity, this innovation accelerates the transition of QLEDs from research to market, promising profound impacts on the consumer electronics and lighting industries.
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References
DOI
Original Source URL
https://doi.org/10.1016/j.esci.2023.100227
Funding information
This work was supported by NSFC (Nos. 62261160392, 52131304, 61725402, U1605244, 22279059), the Fundamental Research Funds for the Central Universities (Nos. 30921011106, 30919012107), the Research Innovation Program of Nanjing Overseas Returnees (No. AD411025), the start-up funding from the Nanjing University of Science and Technology, the Jiangsu Funding Program for Excellent Postdoctoral Talent (No. 2023ZB844), and the China Postdoctoral Science Foundation (No. 2023M731687). The authors are also thankful for the support from the NJUST large instrument equipment open fund and Vacuum Interconnect Nano X Research Facility (NANO-X) of Suzhou Institute of Nano-Tech and Nano-Bionics, CAS.
About eScience
eScience – a Diamond Open Access journal (free for both readers and authors before 2026) cooperated with KeAi and published online at ScienceDirect. eScience is founded by Nankai University and aims to publish high-quality academic papers on the latest and finest scientific and technological research in interdisciplinary fields related to energy, electrochemistry, electronics, and environment. eScience has been indexed by ESCI, CAS, DOAJ and Scopus. The First Impact Factor (2023) is 42.9. The founding Editor-in-Chief is Professor Jun Chen from Nankai University. He is an academician of the Chinese Academy of Sciences, a fellow of The World Academy of Sciences. eScience has published 19 issues, which can be viewed at https://www.sciencedirect.com/journal/escience.
