The search for sustainable and affordable energy conversion technologies has highlighted the importance of the oxygen reduction and oxygen evolution reactions (ORR and OER). These processes are crucial for the efficiency of devices like fuel cells and electrolyzers but have traditionally relied on costly noble metals as catalysts. This dependency poses significant barriers to broader adoption and scalability.
In a review (doi: 10.1016/j.esci.2023.100141) published in the journal eScience, a research team from Technische Universität Dresden have reviewed the major advancement in creating effective and affordable electro-catalysts without the use of noble metals for oxygen electrocatalysis in alkaline electrolytes.
The review provides an in-depth analysis of noble metal-free catalysts, focusing on three primary categories: transition metal compounds, single-atom catalysts, and entirely metal-free options. Researchers utilized several innovative strategies to enhance these catalysts’ effectiveness for oxygen electrocatalysis, crucial for energy conversion technologies. Techniques such as heteroatom doping, which introduces different atoms into the catalyst structure, vacancy creation that alters material properties by removing atoms, and strain induction to modify electronic properties, were key. These approaches aimed to improve the catalysts’ physicochemical characteristics, significantly boosting their performance in oxygen reduction and evolution reactions. This research underscores the potential of noble metal-free materials in replacing costly and scarce noble metals traditionally used in catalysts, highlighting a path towards more affordable and sustainable energy conversion devices.
In addition to exploring improvements in oxygen electrocatalysis via electronic structure regulation of non-noble materials, a recent study (doi: 10.1016/j.esci.2023.100118) published in the same journal by researchers from the University of Technology Sydney and the Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences has made significant advances in materials for energy conversion and storage. They have introduced a method for synthesizing metal-organic framework (MOF)-derived nanocages, which considerably enhance the efficiency of water oxidation and selective ethylene glycol reformation, marking a notable progress in the field of sustainable energy production.
The studies introduce innovative materials and techniques to improve the efficiency of processes such as water electrolysis for hydrogen production, contributing to the evolution of energy conversion and storage technologies. These efforts align with the broader goal of developing cost-effective, efficient, and environmentally friendly alternatives to conventional energy sources, thereby supporting the global transition towards renewable energy sources.
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References
DOI
Original Source URL
https://doi.org/10.1016/j.esci.2023.100141
Funding information
This work was financially supported by European Union’s Horizon 2020 research and innovation programme (GrapheneCore3 881603), Sächsisches Staatsministerium für Wissenschaft und Kunst (Sonderzu-weisung zur Unterstützung profilbestimmender Struktureinheiten), German Research Foundation (DFG) within the Cluster of Excellence, and CRC 1415 (grant no. 417590517).
About eScience
eScience – a Diamond Open Access journal (free for both readers and authors before 2025) cooperated with KeAi and published online at ScienceDirect. eScience is founded by Nankai University and aims to publish high-quality academic papers on the latest and finest scientific and technological research in interdisciplinary fields related to energy, electrochemistry, electronics, and environment. eScience has been indexed by DOAJ, Scopus and ESCI. The latest CiteScore is 32.6 in 2024. The founding Editor-in-Chief is Professor Jun Chen from Nankai University. eScience has published 15 issues, which can be viewed at https://www.sciencedirect.com/journal/escience.
