The scientists, at the U.S. Department of Energy’s Critical Materials Institute at Ames Laboratory, in collaboration with the Nebraska Center for Materials and Nanoscience and the Department of Physics and Astronomy at the University of Nebraska, identified orbital-moment quenching as the possible tool, and rationalized the quenching in terms of the dependence of electrical charge distribution in samarium atoms.
Sm-Co magnets were the first rare-earth permanent magnets, and are still the top performer in applications where resistance to demagnetization – its coercivity – and performance at high temperatures are important.
The scientists at first sought to test the limits of substituting iron for some of the cobalt, attempting to make a Sm-Co magnet comparable in strength to neodymium iron boron (Nd-Fe-B) magnets, which has a higher magnetic moment.
“The Critical Materials Institute (CMI) has as one of its moonshots the discovery of materials that are comparable in strength to neodymium magnets, but with the high-temperature durability of samarium magnets,” said Durga Paudyal, Ames Laboratory scientist and project leader for Predicting Magnetic Anisotropy at CMI. “We were looking to increase the magnetic moment of the standard Sm-Co magnet.”
The research collaboration led to the discovery that substitutions of iron could range as high as 20 percent, keeping the coercivity of the magnet intact. Computational theory and modeling results showed that the electronic structure of the Samarium in the material may violate Hund’s rule, which predicts how electrons occupy available orbitals in the atomic structure.
The research findings will help scientists sort out the parameters of magnetism in rare-earth materials, and help speed discovery of potentially useful magnets in the future.
The research is further discussed in “Anisotropy and Orbital Moment in Sm-Co Permanent Magnets,” authored by Bhaskar Das, Renu Choudhary, Ralph Skomski, Balamurugan Balasubramanian, Arjun K. Pathak, Durga Paudyal, and David J. Sellmyer; and published in Physical Review B.
The Critical Materials Institute is a Department of Energy Innovation Hub led by the U.S. Department of Energy’s Ames Laboratory and supported by the Office of Energy Efficiency and Renewable Energy’s Advanced Manufacturing Office, which supports early-stage research to advance innovation in U.S. manufacturing and promote American economic growth and energy security. CMI seeks ways to eliminate and reduce reliance on rare-earth metals and other materials critical to the success of clean energy technologies.
Ames Laboratory is a U.S. Department of Energy Office of Science National Laboratory operated by Iowa State University. Ames Laboratory creates innovative materials, technologies and energy solutions. We use our expertise, unique capabilities and interdisciplinary collaborations to solve global problems.
Ames Laboratory is supported by the Office of Science of the U.S. Department of Energy. The Office of Science is the single largest supporter of basic research in the physical sciences in the United States, and is working to address some of the most pressing challenges of our time. For more information, please visit https://energy.gov/science.